Most all paints will hold up on an engine block. The block itself will never get hot enough to cook the paint off it. You can paint it with just about anything you want. A trick to make spraybomb paint hard as hell is to bake it at 300* for 30 min after it has sat long enough for the surface to dry enough to handle. Just don't let your wife find car parts in the oven. Ask me how I know!
Mike
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Mike Redpath
Musclerodz & Customz
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