I keep reading "cables" as in plural.... I would really hope that you guys are only running ONE cable - as in a positive - forward to either the starter motor or to a post/terminal somewhere up "front".
The whole car - body and chassis - is the ground... with a short ground strap from the batter to somewhere right close to where the battery is mounted.
I then run short ground straps - under the car from the block to the chassis - and another one from the body to the chassis.... so I have good grounds and I'm not relying on bolts and screws. Use a STAR WASHER under the ground - these are made to cut into the paint/primer to give you good metal to metal contact.
When I run cables or wiring thru the floor - I use a marine grade (west marine) bulkhead fitting. There are many types - and their use depends on what you're doing - where - etc. I like the water tight versions that you run the cable thru - and a nut threads on and clamps the cable and also makes it water tight.
BTW -- worrying about a fire in an accident is a bit overkill and over thinking. You don't drive this car daily - reducing your risk 100's fold - which is why your insurance is about 1/3 of your daily driver... yet the value of the Camaro is probably higher. Why? Because of the reduced exposure. Think about the millions of factory cars running around -- they don't or haven't - taken any particular action regarding battery started fires. Batteries are up front - in back - under seats - in trunks...
If you're really worried about that -- think about this - the two terminals are "exposed" -- what if you get in a wreck and the metal around the battery is crushed and shorts out the terminals....
I'm just saying - there's too many scenarios... Just put the battery where you want it and run your cables...